PENCEMARAN SODIUM DODECYLBENZENE SULFONATE (SDBS) PADA IKAN AIR TAWAR: PENENTUAN AKUMULASI DAN MONITORING PENCEMARAN

Monica Cahyaning Ratri

doi:10.24071/jpsc.00563

PENCEMARAN SODIUM DODECYLBENZENE SULFONATE (SDBS) PADA IKAN AIR TAWAR: PENENTUAN AKUMULASI DAN MONITORING PENCEMARAN

Monica Cahyaning Ratri

Abstract

The research for accumulation determination and monitoring of Sodium Dodecylbenzene Sulfonate (SDBS) contamination in freshwater fish has been conducted. The aims of this research were to determine the interference of protein and ions in analysis, the parameters of validation, the correlation of SDBS concentration in the basin and SDBS accumulation in catfish followed by SDBS analysis in freshwater fish that sold in market in the area of Yogyakarta city. This research was started by isolating SDBS from freshwater fish using soxhlet extraction method and then followed by analysis of SDBS using spectrophotometer UV-Vis with acridine orange (AO) reagent. The results showed that the presence of proteins might be interferre the analysis process, Ca²⁺ and Mg²⁺ ions might interfere the analysis process at concentrations > 12 mg/L and > 6 mg/L. Analytical method validation was performed and showed correlation coefficient values (r) was 0,9981, limit of detection was 0,089 mg/L, limit of quantification was 0,0296 mg/L, RSD < 2% and % recovery between 83-107%. The content of the SDBS in fish increased with increasing concentrations of SDBS in water and caused the decrease of Bio-concentration Factor (BCF) value. The concentration of SDBS in the analysis of fish in the market were between 0,0012-0,0029 mg/g, 0,0038-0,0077 mg/g and 0.0008-0,0026 mg/g for catfish, red tilapia and carp, respectively.

Keywords

accumulation; analysis; SDBS; freshwater fish

Full Text:

PDF

References

Ardi, I., 2013. Budidaya ikan sistem keramba jaring apung guna menjaga keberlanjutan lingkungan perairan waduk cirata. Media Akuakultur, 8 (1), 2329.

Arendorf, J., Bojczuk, K., Sims, E., Menkveld, R., Golsteijn, L., Gaasbeek, A., Boyano, A., Medyna, G., dan Kaps, R., 2014. Revision of European Ecolabel Criteria for Laundry Detergents. Institute for Prospective Technological Studies (IPTS).

Britton, L.N., 1998. Surfactants and the Environment. Journal of Surfactants and Detergents, 1 (1), 109117.

Coelho, S. dan Rocha, O., 2010. Assessment of the Potential Toxicity of a Linear Alkylbenzene Sulfonate ( LAS ) to Freshwater Animal Life by Means of Cladoceran Bioassays. Ecotoxicology, 19, 812818.

Dias, C.L., Ala-Nissila, T., Wong-ekkabut, J., Vattulainen, I., Grant, M., dan Karttunen, M., 2010. The Hydrophobic Effect and Its Role in Cold Denaturation. Cryobiology, 60 (1), 9199.

Dietrich, A.M., 2015. EPA Secondary Maximum Contaminant Levels?: A Strategy for Drinking Water Quality and Consumer Acceptability. Philadelphia: Philadelphia Water Departement.

Gassel, M., Harwani, S., Park, J., dan Jahn, A., 2013. Detection of Nonylphenol and Persistent Organic Pollutants in Fish from the North Pacific Central Gyre. Marine Pollution Bulletin, 73 (1), 231242.

Graziano, G., 1999. Hydrophobicity of Benzene. Biophysical Chemistry, 82 (1), 6979.

Harris, D.C., 2010. Quantitative Chemical Analysis. Eight edition. New York: W. H. Freeman and Company All.

Hasibuan, A.P. dan Soewarsono, H., 1999. Pengaruh Pemberian Pakan yang mengandung Testis Sapi pada Pengalihan Jenis Kelamin (Sex-Reversal) Ikan Nila Merah (Oreochromis sp.). Penelitian dan Pengembangan Aplikasi Isotop dan Radiasi, (7), 353357.

Indradjaja, D.D., 2010. Indonesian Aquaculture Report 2010. Jakarta: USDA Foreign Agricultural Service.

Manahan, Stanley E., 2003. Toxixological Chemistry and Biochemistry. Washington, D.C: CRC Press LLC.

Muhamat dan Hidayaturrahman, 2017. Kematian Ikan Nila pada Budi Daya Keramba Jaring Apung di Desa Aranio dan Tiwingan Lama Kabupaten Banjar, Kalimantan Selatan. In: Prossiding Seminar Nasional Masyarakat Biodiversitas Indonesia. 2832.

Muzakar, K., 2016. Analisis Natrium Dodesilbenzena Sulfonat dalam Ikan Lele secara Maserasi dan Spektrofotometri UV-Vis menggunakan Metilen Biru. Tesis. Jurusan Kimia FMIPA UGM. Yogyakarta.

Otzen, D., 2011. Protein-Surfactant Interactions: A Tale of Many States. Biochimica et Biophysica Acta - Proteins and Proteomics, 1814 (5), 562591.

Rust, D. dan Wildes, S., 2008. A Market Opportunity Study Update. Midland, MI: OmniTech International Ltd.

Sez, M., Len, V.M., Gmez-Parra, a., dan Gonzlez-Mazo, E., 2000. Extraction and Isolation of Linear Alkylbenzene Sulfonates and Their Intermediate Metabolites from Various Marine Organisms. Journal of Chromatography A, 889 (12), 99104.

Schmitt, T.M., 2001. Analysis of Surfactant. Second edition. New York: Marcel Dekker Inc.

Susanto, E. dan Fahmi, A S., 2012. Senyawa Fungsional dari Ikan?: Aplikasinya dalam Pangan. Jurnal Aplikasi Teknologi Pangan, 1 (4), 95102.

Tolls, J., Haller, M., dan Sijm, D.T.H.M., 1999. Extraction and Isolation of Linear Alcohol Ethoxylates from Fish. Journal of Chromatography A, 839 (12), 109117.

Turro, N.J. dan Lei, X.-G., 1995. Spectroscopic Probe Analysis of Protein-Surfactant Interactions: the BSA/SDS system. Langmuir, 5 (10), 25252533.

Ubadillah, A. dan Hersoelistyorini, W., 2010. Kadar Protein dan Sifat Organoleptik Nugget Rajungan dengan Substitusi Ikan Lele ( Clarias gariepinus ). Jurnal Pangan dan Gizi, 1 (2).

Versteeg, D.J. dan Rawlings, J.M., 2003. Bioconcentration and Toxicity of Dodecylbenzene Sulfonate (C12LAS) to Aquatic Organisms Exposed in Experimental Streams. Archives of Environmental Contamination and Toxicology, 44 (2), 237246.

Vinodhini, R. dan Narayanan, M., 2008. Bioaccumulation of Heavy Metals in Organs of Fresh Water Fish Cyprinus carpio (Common carp), International Journal of Environmental Science and Technology, 5 (2), 179-182.

Zakaria, R., 2008. Kemunduran Mutu Ikan Gurami ( Osphronemus gouramy ) Pasca Panen pada Penyimpanan Suhu Chilling. Program Studi Teknologi Hasil Perikanan, IPB, Bogor.

DOI: https://doi.org/10.24071/jpsc.00563